Does using an OpenVPN in conjunction with XprivacyLua %100 prevent an app from knowing anything about the Wi-Fi I’m connected to?

Let’s say I don’t want an app to know the network I’m connected to, would using an OpenVPN app and restricting everything for the app on XprivacyLua be as good as using a different Wi-Fi connection than the one I don’t want it to know about?